Cast iron

Iron (Fe) accounts for more than 95% of the alloy material, while the main alloying elements are carbon (C) and silicon (Si). The amount of carbon in cast irons is 2.1 - 4%, while ferrous alloys with less carbon are denoted as carbon steel by definition. Cast irons contain appreciable amounts of silicon, normally 1 - 3%, and consequently these alloys should be considered ternary Fe-C-Si alloys.

Despite this, the principles of cast iron solidification are understood from the binary iron-carbon phase diagram, where the eutectic point lies at 1154 °C and 4.3 wt% carbon. Since cast iron has nearly this composition, its melting temperature of 1150 to 1200 °C is about 300 degrees lower than the melting point of pure iron. Cast iron tends to be brittle, unless the name of the particular alloy suggests otherwise. The color of a fracture surface can be used to identify an alloy: carbide impurities allow cracks to pass straight through, resulting in a smooth, "white" surface, while graphite flakes deflect a passing crack and initiate countless new cracks as the material breaks, resulting in a rough surface that appears grey.

With its low melting point, good fluidity, castability, excellent machinability and wear resistance, cast irons have become an engineering material with a wide range of applications, including pipes, machine and car parts.